How is
Natural Gas Treated to Prepare It for Sales?
Natural gas produced from underground reservoirs must be processed to
remove water, impurities, and heavier hydrocarbons. The impurities are usually hydrogen
sulfide and carbon dioxide. The heavier hydrocarbons or natural
gas liquids (NGLs) are ethane (C2H6),
propane (C3H8), butane (C4H10), and natural
gasoline.
Natural gas liquids are removed from the natural gas feed to recover the
heavier hydrocarbons and to allow the treated gas to move through the pipeline network.
The liquids are removed from the stream because they are more valuable (have higher
prices) as raw materials to produce chemicals and gasoline than they are as fuel. In
addition the heavier liquids can condense out of the natural gas stream and cause problems
in transporting the gas through pipelines.

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Natural gas liquids are recovered using four
different technologies: refrigeration, cryogenic recovery, oil absorption,
and dry-bed adsorption. Natural gas liquids are
recovered by cooling or refrigerating the natural gas
until the liquids are condensed out. The plants use Freon or propane to cool the gas.
Cryogenic recovery
processes are done at temperatures lower
than -150 °F. The low temperatures allow the plant to recover over 90% of the ethane in
the natural gas. Most new gas processing plants use cryogenic recovery technology. Oil absorption is a process used by older gas processing
plants and in many refinery gas plants.

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This
process is not as efficient as cryogenic processing and only
70% propane and all of the butane and natural gasoline are recovered. Dry-bed adsorption is used to remove water and some
of the natural gas liquids from the natural gas. The liquids are adsorbed on the surface
of the desiccant such as silica gel. Desiccants
are added to many products, such as medicines, to keep them dry. The adsorption process
recovers 10 - 15% of the butane and 50 - 90% of the natural gasoline. After removal from
the natural gas stream, the natural gas liquids are separated in a series of distillation
towers into their primary components: ethane, propane, butane, and natural gasoline.
Natural
Gas Liquids Boiling Points
|
Chemical |
Boiling
Point |
| Methane |
-259 oF. |
| Ethane |
-128 oF. |
| Propane |
- 44 oF. |
| Isobutane |
10.9 oF. |
| Normal Butane |
31.1 oF. |
| Isopentane |
82.2 oF. |
| Normal Pentane |
96.9 oF. |
The
following table indicates the distribution of
natural gas liquids in the marketplace. The major product uses are for petrochemical and
refinery feed stocks to produce products like ethylene, propylene,
butylene, and gasoline.
The main use of propane is in fuel applications such as home heating in places that are
not served by natural gas pipelines and fuel for outdoor cooking.
Natural
Gas Liquids Products and Markets
Markets
(Percent of Consumption)
|
Product |
Petrochemical
Feed Stock |
Domestic
and
Industrial Fuel |
Refinery
Feed Stock |
Other |
| Ethane |
97.0 |
1.5 |
0 |
1.5 |
| Propane |
42.0 |
52.0 |
0 |
6.0 |
| n-Butane |
21.0 |
0 |
66.0 |
13.0 |
| i-Butane |
43.0* |
0 |
57.0 |
0 |
| Natural Gasoline |
28.0 |
0 |
44.0 |
28.0 |
* Includes MTBE
Source: J. Richard Moore
To
learn more about natural gas
processing,
please check out the following PetroStrategies
classes:
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For more information
about natural gas processing, check out the
following references:
Updated 11/27/07
Copyright 2000
PetroStrategies, Inc.
All rights reserved
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